Assertion : Aniline is a better nucleophile t | vedclass

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(A) nucleophile is a species that donates a lone pair of electrons.In aniline $(C_6H_5NH_2)$,the nitrogen atom has a lone pair of electrons available

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If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.

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(A) nucleophile is a species that donates a lone pair of electrons.In aniline $(C_6H_5NH_2)$,the nitrogen atom has a lone pair of electrons available for donation.In the anilinium ion $(C_6H_5NH_3^+)$,the lone pair of the nitrogen atom is involved in bond formation with a proton $(H^+)$,resulting in a positive charge on the nitrogen.Because the anilinium ion carries a positive charge and lacks an available lone pair,it cannot act as a nucleophile.Therefore,aniline is a much better nucleophile than the anilinium ion.Both the assertion and the reason are correct,and the reason correctly explains why the anilinium ion is not a nucleophile.

Assertion : Aniline is a better nucleophile than anilinium ion.
Reason : Anilinium ion has a positive charge.

Similar Questions

Which of the following is the most stable species?

What is the color of the precipitate formed when aniline reacts with $HNO_2$ at low temperature,followed by treatment with an alkaline $\beta$-naphthol solution?

Which of the following is the least basic?

The correct order of basicity in amines is:
$(i)$ $C_6H_5NH_2$
$(ii)$ $CH_3NH_2$
$(iii)$ $(CH_3)_2NH$
$(iv)$ $(CH_3)_3N$

The decreasing order of the basic character of the following amines and ammonia is:

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Assertion : Aniline is a better nucleophile than anilinium ion.Reason : Anilinium ion has a positive charge.